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This is the most in depth explanation I have found on LiPo batteries
Why do LiPo Battery swell
What causes a LiPo battery to swell?
To understand why a LiPo battery (or any other battery, for that matter) swells, we need to understand how its individual components interact to make the battery work. All batteries are made with three basic components: a negative end, a positive end, and an electrolyte solution. Batteries conduct electricity via the migration of ions from the positive end to the negative end and vice-versa. These ions can travel through the electrolyte solution.
LiPo batteries are distinct from the old-fashioned lithium-ion batteries due to their use of a solid polymer electrolyte. Through this solid electrolyte, lithium ions can move between the two terminals of a LiPo battery. A LiPo battery also has polymer separator that keeps the positive and negative terminals from coming into contact with each other.
Batteries swell because of the phenomenon of electrolyte decomposition. As its name implies, this is the process where the electrolyte solution decomposes into its individual components. In most cases, these components include oxygen. In the case of LiPo batteries, the polymeric nature of the electrolyte means that they also tend to produce carbon dioxide (CO2) and carbon monoxide (CO) when they decompose. The production of these gases is what causes a LiPo battery to expand and swell.
There have been a lot of instances of LiPo batteries catching fire while they are plugged in. The chances of a LiPo battery charging fire is even higher once electrolytic decomposition has kicked in, as the oxygen-rich gases are very flammable, A good practice to follow is once your LiPo battery has indicated that the battery is full, disconnect the battery and switch the charger off at the wall, and never leave the battery connected to the charger unattended.
One thing to remember about battery swelling is that it cannot be avoided. Electrolyte decomposition is a naturally occurring process, albeit it should be a slow one. However, improper maintenance of the battery can accelerate the decomposition process.
What should I do with a swollen LiPo battery?
The first thing you should know is that a swollen LiPo battery is a lost cause. You cannot fix it, and you should look for a replacement battery as soon as possible. Once you have decided to stop using your swollen LiPo battery, you should dispose of it properly. |
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